Deuterium Substitution and Solvent Effects on Reaction Dynamics in Extended-nano Spaces on a Chip

نویسندگان

  • Takehiko Tsukahara
  • Kyosuke Nagaoka
  • Takehiko Kitamori
چکیده

We have investigated deuterium-substitution and solvent effects for the keto-enol tautomerization of acetylacetone (Hacac) confined in 10 – 100 nm scale spaces (called extended-nano spaces) based on NMR spectroscopic results, and elucidated the tautomeric reaction mechanisms in the extended-nano spaces.

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تاریخ انتشار 2008